Foundation of Thermoelectric Cooling
This section introduces the core principles of Peltier modules. It establishes that TECs are not cold generators, but solid-state heat pumps reliant on the efficiency of dual-heatsink architectures.
The Heat Pump Concept
TECs facilitate a directional transport of phonons and charge carriers across Bismuth Telluride (Bi2Te3) junctions. The efficiency is governed by the Figure of Merit (ZT):
A high ZT requires materials with high electrical conductivity (σ) to minimize Joule heating, and low thermal conductivity (k) to prevent Fourier heat backflow.
Governing Equations
The net cooling capacity (Qc) absorbed at the cold junction is defined by:
The heat rejected at the hot junction (Qh) includes electrical work:
Fundamental Asymmetry: Qh ≫ Qc